Polymeric Based Materials via Palladium- Catalyzed Polycondensation
JUNIPER PUBLISHERS- ACADEMIC JOURNAL OF POLYMER SCIENCE Abstract The significant access to the structurally pure, high molar mass, N-containing polymers via palladium-catalyzed polycondensation of various aromatic diamines with various aromatic dibromo compounds is an interesting target. One of the major advantages is to apply inexpensive monomers; aromatic amines and aromatic bromides. Furthermore, many diamines are readily available or easy to synthesize giving fast access to numerous new functionalized polymers either by applying amino-functionalized or bromo-functionalized monomers to optimize and improve the polymer properties. With the increasing demand for different functionalized polymers, the focus of relevant studies has been to generate polymers with improved properties by palladium-catalyzed polycondensation. A series of poly(imino ether)s (PIEs), poly(imino ketone)s (PIKs), poly(imino azobenzene)s (PIAzos), poly(imino acridine)s (PIAcs), poly(imino fluor...